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991.
992.
引言在定量和定性研究有机化合物的结构与性质的关系中,最广泛使用的是Hammett等所提出的σ_m、σ_p等取代基常数以及基团的诱导(场)效应和共轭效应常数。在建立基团的共轭效应常数方面,人们做了大量的工作,但多数工作是基于对基团的Hammett常数σ的人为分解上,建立的模型和分解方式(系数因子)不同,则得到不同的结果。另一方面纯理论计算工作大多引入较多参数,使计算复杂和使用不便。作者曾在建立表征诱导效应大小的 相似文献
993.
微通道板增益疲劳机理研究 总被引:2,自引:0,他引:2
微通道板的增益疲劳是微通道板的主要问题之一,本文分析了微通道板的表面结构模型,同通道板活性表面上碱金属的逸出和碳的增加是导致微通道板的增益疲劳的主要原因,另外,探讨碱金属逸出的机理和碳污染的来源,介绍延长微通道板工作寿命的有效方法。 相似文献
994.
A solution to the BBGKY hierarchy for nonequilibrium distribution functions is obtained within modified boundary conditions. The boundary conditions take into account explicitly both the nonequilibrium one-particle distribution function as well as local conservation laws. As a result, modified group expansions are proposed. On the basis of these expansions, a generalized kinetic equation for hard spheres and a generalized Bogolubov–Lenard–Balescu kinetic equation for a dense electron gas are derived within the polarization approximation. 相似文献
995.
Santanu Bhattacharya Basudeb Saha Amitava Dutta Pradyot Banerjee 《Coordination chemistry reviews》1998,170(1):47-74
This review narrates the electron transfer reactions of various nickel(III) and nickel(IV) complexes reported during the period 1981 until today. The reactions have been categorized mainly with respect to the type of nickel complexes. The reactivity of nickel(III) complexes of macrocycles, 2,2′-bipyridyl and 1,10-phenanthroline, peptides and oxime–imine, and of nickel(IV) complexes derived from oxime–imine, oxime and miscellaneous ligands with various organic and inorganic electron donors have been included. Kinetic and mechanistic features associated with such interactions have been duly analyzed. The relevance of Marcus cross-relation equations in the delineation of the electron transfer paths has also been critically discussed. 相似文献
996.
997.
Applying a Lindemann like criterion obtained previously by Kierfeld et al. [J. Kierfeld, T. Nattermann, T. Hwa, Phys. Rev. B 55 (1997) 626], we estimate the magnetic field and temperature for a high-Tc superconductor, at which a topologically ordered vortex glass phase becomes unstable with respect to a disorder-induced formation of dislocations. The employed criterion is shown to be equivalent to a conventional phenomenological Lindemann criterion including the values for the numerical factors, i.e., for the Lindemann number. The positional correlation length of the topologically ordered vortex glass is calculated. 相似文献
998.
Alexander I. Roshchin Sergey M. Kelchevski Nikolai A. Bumagin 《Journal of organometallic chemistry》1998,560(1-2)
Substituted 2-methylbenzofurans were obtained from 2-allylphenols via Pd2+-catalyzed oxidative cyclization using Cu(OAc)2–LiCl as a reoxidant and wet DMF as a solvent. 相似文献
999.
1000.
Danch A. Lohner K. Ungerank M. Stelzer F. 《Journal of Thermal Analysis and Calorimetry》1998,54(1):161-170
Bis [(ω-(4′-cyanobiphenyl)-4-yl)oxy-n-alkyl]norborn-5-ene-2,3-dicarboxylate was polymerised via ring opening metathesis polymerisation
(ROMP). Two disubstituted polynorbornene derivatives both of cis configuration with different length of the side-chain were
studied. Differential scanning calorimetry (DSC) was used to study the effect of thermal history on the assignment of the
glass transition event associated with the biaxial orientation of a smectic phase. Glass transition temperatures, the change
of isobaric specific heats at Tg and the enthalpies of isotropisation were calculated. The DSC traces only show the classic step-wise change in Tg in some cases, giving the evidence that the amorphous domains are constrained and highly restricted in movement due to the
morphology developed as a result of the biaxial stretching. Based on the literature data of mono- and disubstituted polynorbornene
derivatives and our calorimetric experiments, the shape of Tg dependence on number of (CH2) units is interpreted. The origin of this shape is discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献